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Thread: Anti reflection coating by dipping process

  1. #1
    Nixg nixg's Avatar
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    Blue Jumper Anti reflection coating by dipping process

    Hi to all,

    Does any body know about Anti reflection coating by dipping process.
    If yes will it be durable on plastic ophthalmic lenses.

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    Underemployed Genius Jacqui's Avatar
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    I have heard that "someone" is working on this. I haven't heard anymore about it, but it sounds very interesting to me.

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    Master OptiBoarder OptiBoard Gold Supporter DragonLensmanWV's Avatar
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    I remain skeptical.
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    Underemployed Genius Jacqui's Avatar
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    Quote Originally Posted by DragonLensmanWV View Post
    I remain skeptical.
    Why?? It's coming or something similar. It should be better than Chemlux, but probably not as good as Carat or other premiums. Chris Ryser's company could probably make one if they would think about it.

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    It would certainly be a "different" technology. My brain isn't functioning too well today, but I can't imagine how or what this would be like.

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    Underemployed Genius Jacqui's Avatar
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    Quote Originally Posted by MikeAurelius View Post
    It would certainly be a "different" technology. My brain isn't functioning too well today, but I can't imagine how or what this would be like.
    It would be a dip and bake process. Probably 5 or 6 stages.

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    How would you control the thickness of the layers to quarter-wave tolerances?

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    Master OptiBoarder OptiBoard Gold Supporter DragonLensmanWV's Avatar
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    How would you eliminate runs?
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    Rochester Optical WFruit's Avatar
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    These questions and many others are the part that they are "working" on.

    Interesting article here: http://ieeexplore.ieee.org/Xplore/lo...hDecision=-203
    There are rules. Knowing those are easy. There are exceptions to the rules. Knowing those are easy. Knowing when to use them is slightly less easy. There are exceptions to the exceptions. Knowing those is a little more tricky, and know when to use those is even more so. Our industry is FULL of all of the above.

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    Manuf. Lens Surface Treatments
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    Blue Jumper You just spin the lens while applying the coating material...........................

    Quote Originally Posted by DragonLensmanWV View Post

    How would you eliminate runs?
    that would be the easiest of all problems to be solved. You just spin the lens while applying the coating material, called spincoating.

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    Blue Jumper There is presently a chemical AR coating marketed.............................

    There is presently a chemical AR coating marketed for photovoltaic cells that is applicable on glas only. Will probably not be long until somebody comes up with the hardcoat as intermediary, that is used on optical lenses.

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    Master OptiBoarder rinselberg's Avatar
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    Quote Originally Posted by DragonLensmanWV View Post
    How would you eliminate runs?
    Quote Originally Posted by Chris Ryser View Post
    that would be the easiest of all problems to be solved. You just spin the lens while applying the coating material, called spincoating.
    Chemalux sells spin-coating units for applying SR, AR and Mirror to ophthalmic lenses.
    http://www.chemat.com/chemalux/

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    Organic AR Coatings are being produced and companies like Seiko have products aready being marketed.

    Seiko released "Orgatech" which is an Nanocomposite organic AR coating and you will start to see more of this new breed of AR coatings coming. The main advantage is the coating is more flexible and thus more durable over the life of the lens. These coatings are more heat resistant and will result in less returns due to crazing and processing issues.

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    Master OptiBoarder OptiBoard Gold Supporter DragonLensmanWV's Avatar
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    I do spin coating here. This is being referred to as dip coating, entirely different.
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    Underemployed Genius Jacqui's Avatar
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    Nidek also makes a beautiful spin coat AR system, but it's not what I was talking about. A dip and bake system was supposed to be on exhibit at Expo Spring 2010. I don't know any more about it, the info is on my old computer and it is DEAD. If I can find more I'll send it along.

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    Dip ar

    At this time I am not aware of a dip AR. If possible it would be very heavy coating vs a AR coating done in a vacuum chamber. Dip coatings today are primarily used as a hard coat with or a primer with a thermal cure cycle. Hard coat on a lenses is a plus as it aids in the adhesion of a AR coating.


    Mirror man

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    ATO Member HarryChiling's Avatar
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    Look into Sol-Gel for info about dip coating AR's.
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    Quote Originally Posted by nixg View Post
    Hi to all, Does any body know about Anti reflection coating by dipping process.
    If yes will it be durable on plastic ophthalmic lenses.

    The lenses aren't "dipped" so much as the liquid is raised to the lens - this is quite an old fashioned technique for applying a finish to a lens, and prone with problems (pitting, peeling, loss of ar properties and more.

    May I ask why you want to find this?

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    Master OptiBoarder LENNY's Avatar
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    Quote Originally Posted by Chris Ryser View Post
    There is presently a chemical AR coating marketed for photovoltaic cells that is applicable on glas only. Will probably not be long until somebody comes up with the hardcoat as intermediary, that is used on optical lenses.
    Already out there Photo Hard coating!

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    I've worked on wet applied (spin and dip) AR coatings for ophthalmics though my work in ophthalmics ended about 5 years ago. There have been at least two broadly commercialized wet applied AR processes. One was dip and was, in my opinion, a non-starter due to poor thickness uniformity (which shows up as reflected color variation across the surface of the lens). The other was spin applied and produced a much more attractive final product however durability was questionable. Both companies used a fairly standard metalorganic sol-gel approach; I believe both companies are now defunct.

    As was mentioned above the most viable technology candidate right now is the organic-inorganic nano-composite approach. I haveworked on this extensively (and have a couple of patents). It's a great approach for half of the material in a typical AR coating stack (low index SiO2 replacements), it's not a great approach for the high index layers (TiO2/ZrO2/Nb2O5 in vacuum deposited AR coatings) because getting a suitably high refractive index is not possible with currently available materials. The consequence is that the AR optical performance is not as good as a vacuum applied stack. There is a much, much larger market than ophthalmics driving the development of these coatings (flexible displays as well as displays for pocket/portable/tablet devices like the iPad) so R&D is well funded and will probably result in substantial improvements over the coming few years.

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    Quote Originally Posted by HarryChiling View Post
    Look into Sol-Gel for info about dip coating AR's.

    You are right. A french company is producing an easy to clean/anti reflect coating by dip. I'm agree that they cannot reach the level of reflectance of process vaccum deposition but they can reach a reflectance of 99% with two layers and 98% with one layer. It's a economic alternative to the PVD process and for PC lenses.

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    My friend has developed such a system for dip coating AR (more of an LR). He has had pretty good results and has sold several systems already.

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    What is LR?
    Is this available in the USA if so where?

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    Underemployed Genius Jacqui's Avatar
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    Quote Originally Posted by Don Gilman View Post
    What is LR?
    Is this available in the USA if so where?
    Low Relection. Maybe Reduced Reflection. It would reduce reflections, but not as well as AR does.

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    Quote Originally Posted by Don Gilman View Post
    What is LR?
    Is this available in the USA if so where?
    I am pretty sure he has not sold to the US market yet.

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